Detailed chemical kinetic modeling of fuel-rich trichloroethane/oxygen/argon flames

Detailed chemical kinetic modeling of fuel-rich trichloroethane/oxygen/argon flames
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DOI:
10.1021/es00181a009
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发表时间:
1989-04
影响因子:
11.4
通讯作者:
W. Chang;S. Senkan
W. Chang;S. Senkan
中科院分区:
环境科学与生态学1区
文献类型:
--
作者:
W. Chang;S. Senkan

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A detailed chemical kinetic mechanism for the com-bustion of C2HC13 under fuel-rich and slightly sooting conditions has been developed. This mechanism was used to calculate the stable species concentration profiles in atmospheric pressure, premixed, one-dimensional flat flames of C2HCl3/02/Ar measured previously (1). The agreement between the model and experimental data is generally reasonable. The major reaction pathways re-sponsible for the formation and destruction of species have been identified via the calculationreaction rates and sensitivity analysis.