Chiral phebox-rhodium complexes as catalysts for asymmetric direct aldol reaction
Chiral phebox-rhodium complexes as catalysts for asymmetric direct aldol reaction
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DOI：
10.1016/j.tet.2007.11.022
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发表时间：
2008-01-14
期刊：
影响因子：
2.1
通讯作者：
Nishiyama, Hisao
中科院分区：
文献类型：
--
作者：
Inoue, Hiroko;Kikuchi, Makoto;Nishiyama, Hisao
手性双（恶唑啉基）苯基铑配合物作为催化剂与AgOTf结合，使酮类与芳醛类直接醛缩反应生成具有高抗选择性和对映选择性高达91%的β -羟基酮。(c) 2007 Elsevier Ltd.版权所有。
Chiral bis(oxazolinyl)phenyl-rhodium complexes act as catalysts in the combination of AgOTf for direct aldol reaction of ketones and aromatic aldehydes to give the corresponding beta-hydroxyketones in high anti-selectivity and a good to high enantioselectivity up to 91% ee. (c) 2007 Elsevier Ltd. All rights reserved.