Effective nonenzymatic kinetic resolution of (′)-trans-2-arylcyclohexanols using 3β-acetoxyetienic acid, DCC, and DMAP
Effective nonenzymatic kinetic resolution of (′)-trans-2-arylcyclohexanols using 3β-acetoxyetienic acid, DCC, and DMAP
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DOI：
10.1021/op0200928
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发表时间：
2003-05
影响因子：
3.4
通讯作者：
M. Matsugi;Y. Hagimoto;M. Nojima;Y. Kita
中科院分区：
文献类型：
--
作者：
M. Matsugi;Y. Hagimoto;M. Nojima;Y. Kita
(1R通过在室温下简单搅拌相应的（±）-芳基环己醇与3β-乙酰氧乙酸、DCC和DMAP，得到了高对映体纯度的（2S）-反式-2-芳基环己醇。
(1R,2S)-trans-2-Arylcyclohexanols of high enantiomerically purity were obtained by the simple stirring of the corresponding (±)-arylcyclohexanols with 3β-acetoxyetienic acid, DCC, and DMAP at room temperature.