REDUCTION OF ISOQUINOLINE AND PYRIDINE-CONTAINING HETEROCYCLES WITH LITHIUM TRIETHYLBOROHYDRIDE (SUPER-HYDRIDE(R))
REDUCTION OF ISOQUINOLINE AND PYRIDINE-CONTAINING HETEROCYCLES WITH LITHIUM TRIETHYLBOROHYDRIDE (SUPER-HYDRIDE(R))
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DOI：
10.1016/s0040-4039(00)79297-5
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发表时间：
1993-11-05
影响因子：
1.8
通讯作者：
CARROLL, FI
中科院分区：
文献类型：
--
作者：
BLOUGH, BE;CARROLL, FI
用三乙基硼氢化锂(Super-Hydride(R))将异喹啉、喹啉和吡啶分别有效地还原为1,2,3,4-四氢异喹啉、1,2,3,4-四氢喹啉和哌啶。通过用三乙基硼氘化锂(Super-Deuteride(R))还原异喹啉和吡啶探索了还原机理。
Isoquinolines, quinoline and pyridines are effectively reduced to 1,2,3,4-tetrahydroisoquinolines, 1,2,3,4-tetrahydroquinolines and piperidines respectively with lithium triethylborohydride (Super-Hydride(R)). The mechanism of the reduction was explored by reduction of isoquinoline and pyridine with lithium triethylborodeuteride (Super-Deuteride(R)).