Electrosynthesis of Conducting Mixed-Valence 9,9'-Dimethyl-3,3'-bicarbazyl Rectangular Nanotubes

Electrosynthesis of Conducting Mixed-Valence 9,9'-Dimethyl-3,3'-bicarbazyl Rectangular Nanotubes
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导电混合价9,9-二甲基-3,3-联咔唑矩形纳米管的电合成

DOI:
10.1039/c2ra01029a
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发表时间:
2012
期刊:
影响因子:
3.9
通讯作者:
H. Masu
H. Masu
中科院分区:
化学3区
文献类型:
--
作者:
K. Hoshino;K. Takizawa;M. Kubo;K. Murashiro;N. Aoki;Y. Ochiai;H. Masu

文献摘要

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一个没有长烷基链的低分子质量分子,一个混合价的9,9 ' -二甲基-3,3 ' -重卡巴基,通过在甲醇中一步电氧化其前体9-甲基咔唑而自组装成高度规则的直微/纳米管,而不需要模板。研究了成管的驱动力。
A low-molecular-mass molecule with no long alkyl chain, a mixed-valence 9,9′-dimethyl-3,3′-bicarbazyl, is self-assembled into highly-regular straight micro/nanotubes by the one-step electro-oxidation of its precursor, 9-methylcarbazole, in methanol without templates. The driving force of the tube formation is investigated.