1-[(Z)-1-Bromo-2-(butyl-dichloro-λ-tellan-yl)ethen-yl]cyclo-hex-1-ene.
1-[(Z)-1-Bromo-2-(butyl-dichloro-λ-tellan-yl)ethen-yl]cyclo-hex-1-ene.
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DOI：
10.1107/s1600536811023142
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发表时间：
2011-07-01
期刊：
影响因子：
--
通讯作者：
Tiekink ER
中科院分区：
文献类型：
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作者：
Zukerman-Schpector J;Caracelli I;Guadagnin RC;Stefani HA;Tiekink ER
The TeIV atom in the title compound, [Te(C4H9)(C8H10Br)Cl2] or C12H19BrCl2Te, is in a distorted ψ-trigonal–bipyramidal geometry, with the lone pair of electrons projected to occupy a position in the equatorial plane, and with the Cl atoms being mutually trans [172.48 (4)°]. Close intramolecular [Te⋯Br = 3.3444 (18) Å] and intermolecular [Te⋯Cl = 3.675 (3) Å] interactions are observed. The latter lead to centrosymmetric dimers which assemble into layers in the bc plane. The primary connections between layers are of the type C—H⋯Cl.
