Synthesis, structure, and reactions of a nitroxyl complex of iridium(III), cis,trans-IrHCl2(NH=O)(PPh3)2
Synthesis, structure, and reactions of a nitroxyl complex of iridium(III), cis,trans-IrHCl2(NH=O)(PPh3)2
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DOI:
10.1039/b111645b
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发表时间:
2002-01-01
影响因子:
4.9
通讯作者:
Hillhouse, GL
中科院分区:
文献类型:
--
作者:
Melenkivitz, R;Hillhouse, GL
Reaction of Ir(NO)(PPh3)(3) with anhydrous HCl results in addition of 2 equivalents of HCl with formal protonation of the nitrosyl ligand, affording the unusual six-co-ordinate nitroxyl complex cis,trans-IrHCl2(NH=O)(PPh3)(2).