An experimentally derived model for stereoselectivity in the aerobic oxidative kinetic resolution of secondary alcohols by (sparteine)PdCl2.
An experimentally derived model for stereoselectivity in the aerobic oxidative kinetic resolution of secondary alcohols by (sparteine)PdCl2.
复制标题
(金豆石)PdCl2 仲醇有氧氧化动力学拆分中立体选择性的实验衍生模型。
DOI：
10.1021/ja039551q
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发表时间：
2004
影响因子：
15
通讯作者：
B. Stoltz
中科院分区：
文献类型：
--
作者：
Raissa M. Trend;B. Stoltz
描述了钯催化有氧氧化动力学分解中的不对称诱导模型。该模型基于母体 (sp)PdCl2 催化剂的配位配合物和一般反应活性趋势。提出了非外消旋手性烷醇钯配合物的第一个例子，并展示了 C1 对称配体金雀花石的微妙空间影响。
A model for asymmetric induction in palladium-catalyzed aerobic oxidative kinetic resolution is described. The model is based on coordination complexes and general reactivity trends of the parent (sp)PdCl2 catalyst. The first example of a nonracemic chiral palladium alkoxide complex is presented, and exhibits the subtle steric influences of the C1 symmetric ligand sparteine.