Efficient optical resolution of water-soluble self-assembled tetrahedral M4L6 cages with 1,1'-bi-2-naphthol.
Efficient optical resolution of water-soluble self-assembled tetrahedral M4L6 cages with 1,1'-bi-2-naphthol.
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DOI：
10.1039/c4cc04145c
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发表时间：
2014-11
影响因子：
4.9
通讯作者：
Shigang Wan;Li-Rong Lin;Li-Li Zeng-Li;Yiji Lin;Hui Zhang
中科院分区：
文献类型：
--
作者：
Shigang Wan;Li-Rong Lin;Li-Li Zeng-Li;Yiji Lin;Hui Zhang
本文利用(R)-/(S)-1,1'-bi-2-萘酚成功地将水溶性外消旋自组装四面体笼[Fe4L6](4-)拆分成ΔΔΔΔ和ΛΛΛΛ对映体。解析的 Fe(II) 笼的对映体过量为 99%。
In this paper, a water-soluble racemic self-assembled tetrahedral cage [Fe4L6](4-) was successfully resolved into their ΔΔΔΔ and ΛΛΛΛ enantiomers by (R)-/(S)-1,1'-bi-2-naphthol. The enantiomeric excess of the resolved Fe(II) cage was 99%.