Correlating thermochromic and mechanochromic phosphorescence with polymorphs of a complex gold(i) double salt with infinite aurophilicity
Correlating thermochromic and mechanochromic phosphorescence with polymorphs of a complex gold(i) double salt with infinite aurophilicity
复制标题
将热致变色和机械致变色磷光与具有无限亲金性的复杂金（I）复盐的多晶型相关联
DOI：
10.1039/c8cc05210g
复制
发表时间：
2018-11-25
影响因子：
4.9
通讯作者：
Lu, Wei
中科院分区：
文献类型：
--
作者：
Liu, Qi;Xie, Mo;Lu, Wei
A complex [Au(NHC)(2)][Au(C?N)(2)] double salt exhibits polymorphic crystalline structures with distinct phosphorescence and variations at AuAu distances and ligand-ligand torsion angles. This serves as a model system correlating aurophilicity and low-energy charge-transfer electronic transitions and helps to understand the thermochromism and mechanochromism of the gold(i) complexes.
