Structure of Dicarbonyl(~/S-cyclopentadienyl)l(diethyldithiocarbamato)- mercurio 1 (trimeth yl phosphite)molybdenum(II)(Mo-Hg)

Structure of Dicarbonyl(~/S-cyclopentadienyl)l(diethyldithiocarbamato)- mercurio 1 (trimeth yl phosphite)molybdenum(II)(Mo-Hg)
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二羰基(~/S-环戊二烯基)l(二乙基二硫代氨基甲酸酯)-汞1(亚磷酸三甲酯)钼(II)(Mo-Hg)的结构

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发表时间:
1991
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通讯作者:
M. Qian
M. Qian
中科院分区:
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文献类型:
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作者:
M. Qian

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ClOH14OsP)MoHg(CsHloNS 2)),Mr = 689.99,单斜晶系,P21/n,a=8.853(1),B= 9.873(2),c=25.231(4)A,fl =97.09(1)°,V= 2188.2A3,Z = 4,Dx = 2.094Mgm-3,A(Mo Kay)= 0.71073/~,在2676个观测反射和235个参数中,λ = 7.277mm-1,F(000)= 1320,T= 296(1)K,最终R = 0.029。该结构是由离散的分子组成的,没有分子间的汞。一般在 * 中观察到的相互作用,通信应发送给谁。
CloH14OsP)MoHg(CsHloNS2)), Mr = 689.99, monoclinic, P21/n, a=8.853 (1), b= 9.873 (2), c=25.231(4) A, fl =97.09(1) °, V= 2188.2 A 3, Z = 4, Dx = 2.094 Mg m -3, A(Mo Kay) = 0.71073/~, /~ = 7.277 mm -1, F(000) = 1320, T= 296 (1)K, final R = 0.029 for 2676 observed reflec- tions and 235 parameters. The structure is built of discrete molecules without the intermolecular Hg...S interactions which are generally observed in the * To whom correspondence should be addressed.