Carbon/carbon nanocomposites fabricated by base catalyzed twin polymerization of a Si-spiro compound on graphite sheets

Carbon/carbon nanocomposites fabricated by base catalyzed twin polymerization of a Si-spiro compound on graphite sheets
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DOI:
10.1039/c2cc34775j
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发表时间:
2012-01-01
影响因子:
4.9
通讯作者:
Spange, Stefan
Spange, Stefan
中科院分区:
化学2区
文献类型:
--
作者:
Ebert, Thomas;Cox, Gerhard;Spange, Stefan

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石墨上的无缺陷微孔碳层可以通过在淤浆聚合中DABCO催化的2,2 '-螺[4 H-1,3,2-苯并二氧杂环己硅烷]的双聚合和随后将所得酚醛树脂热转化为碳来制备。
Defect-free microporous carbon layers on graphite can be produced by DABCO-catalyzed twin polymerization of 2,2'-spirobi[4H-1,3,2-benzodioxasiline] in a slurry polymerization and subsequent thermal transformation of the resulting phenolic resin into carbon.