Two-dimensional metamagnet composed of cyano-bridged CuII-WV bimetallic assembly.

Two-dimensional metamagnet composed of cyano-bridged CuII-WV bimetallic assembly.
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DOI:
10.1039/b310456g
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发表时间:
2003-10
影响因子:
4.9
通讯作者:
S. Ohkoshi;Yoichi Arimoto;T. Hozumi;H. Seino;Y. Mizobe;K. Hashimoto
S. Ohkoshi;Yoichi Arimoto;T. Hozumi;H. Seino;Y. Mizobe;K. Hashimoto
中科院分区:
化学2区
文献类型:
--
作者:
S. Ohkoshi;Yoichi Arimoto;T. Hozumi;H. Seino;Y. Mizobe;K. Hashimoto

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二维氰化物桥连八氰基钨酸铜(II)[(Cu(3-CNpy)2(H2O))2(Cu(3-CNpy)2(H2O)2)(W(CN)8)2](3-CNpy = 3-氰基吡啶)⑴和[(Cu(4-CNpy)2)2(Cu(4-CNpy)2(H2O)2)(W(CN)8)2] x 6H2O(4-CNpy = 4-氰基吡啶)(2),这些化合物表现出变磁性,Néel温度分别为8.0K(1)和4.4K(2)。
Two-dimensional cyanide-bridged copper(II) octacyanotungstates(V), [(Cu(3-CNpy)2(H2O))2(Cu(3-CNpy)2(H2O)2)(W(CN)8)2] (3-CNpy = 3-cyanopyridine) (1) and [(Cu(4-CNpy)2)2(Cu(4-CNpy)2(H2O)2)(W(CN)8)2] x 6H2O (4-CNpy = 4-cyanopyridine) (2), were prepared and these compounds exhibited metamagnetic behavior with Néel temperatures of 8.0 K (1) and 4.4 K (2).