Polar Effects of Organosilicon Substituents in Carboxylic Acids
Polar Effects of Organosilicon Substituents in Carboxylic Acids
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DOI：
10.1021/ja01172a521
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发表时间：
1949-04
影响因子：
15
通讯作者：
L. H. Sommer;Jack Gold;G. Goldberg;N. Marans
中科院分区：
文献类型：
--
作者：
L. H. Sommer;Jack Gold;G. Goldberg;N. Marans
含有机硅取代基的羧酸的酸强度与有机分子中有机硅取代基的极性效应有关。本文报道了四种含硅羧酸的合成及其酸强度。
The acid strengths of carboxylic acids containing organosilicon substituents close to the car-boxyl are of interest in connection with an elucidation of the polar effects of such substituents in organic molecules. We wish to report the synthesis and acid strengths of foursilicon-containing carboxylic acids.