A paired carbonate–organic δ13C approach to understanding the Cambrian Drumian carbon isotope excursion (DICE)
A paired carbonate–organic δ13C approach to understanding the Cambrian Drumian carbon isotope excursion (DICE)
复制标题
配对碳酸盐-有机 δ13C 方法来了解寒武纪 Drumian 碳同位素偏移 (DICE)
DOI:
10.1016/j.precamres.2019.105503
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发表时间:
2020-10
影响因子:
3.8
通讯作者:
Yanan Shen
中科院分区:
文献类型:
--
作者:
D;an Li;Xiaolin Zhang;Xu Zhang;Hao Zhu;Shanchi Peng;Lilin Sun;Yanan Shen
The middle Cambrian (Cambrian Series 3) Drumian carbon isotope excursion (DICE) represents a pronounced negative carbon isotopic excursion, and has been proposed as a key chemostratigraphic marker for identifying the base of Cambrian Drumian Stage and global correlation. However, the precise interbasinal correlation of the DICE to the South China remains unsolved and the driving mechanism of the DICE is to be further understood. In this study, we report new paired δ13Ccarband δ13Corgdata from the Wangcun section in South China. Both δ13Ccarband δ13Corgprofiles capture a large negative excursion (DICE) near the FAD ofP. atavus. We suggest that the parallel δ13Ccarband δ13Corgnegative excursions during the DICE may have resulted from the shoaling of anoxic deep waters associated with the transgressive event. Shoreward and upward incursion of deep anoxic waters into oxygenated shallower water column during transgression could lead to the enhanced oxidation of dissolved organic carbon (DOC) and introduce additional13C-depleted carbon to the surface water, resulting in the parallel δ13Ccarband δ13Corgnegative excursions. More importantly, we use a box model to quantify the flux of DOC oxidation needed to produce a carbon isotope excursion of the magnitude and duration of the DICE we observed. The model results indicate that oxidation of DOC during the DICE may require massive amounts of oxidants (i.e., sulfate and oxygen), probably causing further expansion of anoxia in the shallow marine environment. We suggest that shoaling of anoxic water during the DICE could have delayed the recovery of metazoan reef systems from the early–middle Cambrian mass extinctions.
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DOI:
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影响因子:
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