Novel high performance asymmetrical squaraines for small molecule organic solar cells with a high open circuit voltage of 1.12 V.

Novel high performance asymmetrical squaraines for small molecule organic solar cells with a high open circuit voltage of 1.12 V.
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DOI:
10.1039/c3cc46217j
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发表时间:
2013-10
影响因子:
4.9
通讯作者:
--
中科院分区:
化学2区
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带有9-咔唑基取代基的不对称取代的方酸菁ASQC表现出-5.46 eV的极深的HOMO能级和1.65 eV的相对低的带隙,因此使得溶液处理的有机太阳能电池具有高达1.12 V的令人印象深刻的Voc和2.82%的PCE。
An asymmetrically substituted squaraine ASQC bearing a 9-carbazyl substituent exhibits an extremely deep HOMO energy level of -5.46 eV and a relatively low bandgap of 1.65 eV, hence renders solution-processed organic solar cells with an impressive Voc of up to 1.12 V and a PCE of 2.82%.