Thermally Stable Four‐Coordinate Silicon(IV) Complexes with an Si=N Double Bond and an SiN3El Skeleton (El = O, S, Se, Te)

Thermally Stable Four‐Coordinate Silicon(IV) Complexes with an Si=N Double Bond and an SiN3El Skeleton (El = O, S, Se, Te)
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DOI:
10.1002/ejic.201500083
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发表时间:
2015-04
影响因子:
2.3
通讯作者:
Felix M. Mück;A. Ulmer;Johannes A. Baus;C. Burschka;R. Tacke
Felix M. Mück;A. Ulmer;Johannes A. Baus;C. Burschka;R. Tacke
中科院分区:
化学3区
文献类型:
--
作者:
Felix M. Mück;A. Ulmer;Johannes A. Baus;C. Burschka;R. Tacke

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供体稳定的硅烯1与N2O和PhElElPh (El = S, Se, Te)反应形成具有Si=N双键的硅(IV)配合物2-5。化合物2 ~ 5在固态和溶液中通过晶体结构分析和核磁共振波谱进行了结构表征。
The donor-stabilized silylene 1 reacts with N2O and PhElElPh (El = S, Se, Te) to form the respective silicon(IV) complexes 2–5 with an Si=N double bond. Compounds 2–5 were structurally characterized by crystal structure analyses and NMR spectroscopic studies in the solid state and in solution.