Monolithic catalysts with Pd deposited on a structured nickel foam packing

Monolithic catalysts with Pd deposited on a structured nickel foam packing
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钯沉积在结构化泡沫镍填料上的整体式催化剂

DOI:
10.1016/j.cattod.2016.03.017
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发表时间:
2016-09
期刊:
影响因子:
5.3
通讯作者:
Chen Jian-Feng
Chen Jian-Feng
中科院分区:
化学2区
文献类型:
--
作者:
Liu Ya-Zhao;Luo Yong;Chu Guang-Wen;Chen Jian-Feng

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Catalyst activity and selectivity of the multiphase catalytic reactions may be strongly reduced by mass transfer limitations. A rotating packed bed (RPB) reactor can intensify the mass transfer process by 1–3 orders magnitude compared to the traditional reactors, which has great potential for catalytic reactions. The first step of the RPB reactor applied to catalytic reactions is to prepare a monolithic catalyst with excellent mechanical strength. This work selected the structured nickel foam packing as the catalyst substrate and then deposited palladium on the surface of the porous nickel foam packing. The above monolithic catalyst was then characterized by FESEM, EDS, TEM, XRD, ICP, and 3D-CT. In order to know the coating adhesivity, the monolithic catalyst was tested by the ultrasonic vibration in an ultrasonicator tank and scouring experiments in a RPB reactor. Hydrogenation of α-methylstyrene was employed to test its catalytic performance.
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