Dehydrogenation Reactions with 3d Metals
Dehydrogenation Reactions with 3d Metals
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3d 金属的脱氢反应
DOI：
10.1007/3418_2023_96
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发表时间：
2024
期刊：
影响因子：
--
通讯作者：
Brodie C
中科院分区：
文献类型：
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作者：
Brodie C
在过去几年中，将醇催化向上转化为更高价值产品的脱氢工艺继续受到持续关注，并推动在这些工艺中应用更可持续的过渡金属（即地球上丰富的金属）。本章讨论了最近的发展领域的金属配体合作（MLC）和三维过渡金属催化剂的醇重整，以各种产品，如酯，胺，酸，脲，聚脲和聚乙烯亚胺。这些MLC促进的分解过程是获得醇重整产物的成本有效且原子经济的途径，通常仅产生氢作为唯一的副产物。
Dehydrogenative processes for the catalytic up-conversion of alcohols into higher value products have continued to receive sustained attention over the past few years with a drive towards the application of more sustainable transition metals (i.e. earth-abundant metals) within these processes. This chapter discusses the recent developments in the field of metal-ligand cooperative (MLC) and 3d transition metal catalysts for alcohol reformation to various products such as esters, amines, acids, ureas, polyureas and polyethyleneimines. These MLC facilitated dehydrogenative processes are cost-effective and atom-economic routes to alcohol reformation products, often only producing hydrogen as the only by-product.