Transformation from non-to double-interpenetration in robust Cd(II) doubly-pillared-layered metal-organic frameworks
Transformation from non-to double-interpenetration in robust Cd(II) doubly-pillared-layered metal-organic frameworks
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DOI：
10.1039/c4cc07112c
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发表时间：
2014-01-01
影响因子：
4.9
通讯作者：
Barbour, Leonard J.
中科院分区：
文献类型：
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作者：
Aggarwal, Himanshu;Lama, Prem;Barbour, Leonard J.
两个已知的Cd(II)非互穿双柱金属有机骨架在失去晶格溶剂分子后经历了互穿程度的变化，从而产生了双互穿骨架。这一转变是从粉末X射线衍射(PXRD)图谱推断出来的，并得到了来自单晶衍射(SCD)数据的额外证据的支持。
Two known Cd(II) non-interpenetrated doubly-pillared metal organic frameworks are shown to undergo a change of degree of interpenetration upon loss of lattice solvent molecules to yield doubly-interpenetrated frameworks. The conversion is inferred from powder X-ray diffraction (PXRD) patterns and supported by additional evidence from single-crystal diffraction (SCD) data.