SYNTHESES OF STRAPPED PORPHYRINS AND OXYGENATION OF THEIR IRON(II) COMPLEXES
SYNTHESES OF STRAPPED PORPHYRINS AND OXYGENATION OF THEIR IRON(II) COMPLEXES
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DOI：
10.1039/c39760000881
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发表时间：
1976-01-01
影响因子：
--
通讯作者：
PETERS, M
中科院分区：
文献类型：
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作者：
BALDWIN, JE;KLOSE, T;PETERS, M
合成了两种束缚的卟啉，其含有连接2个相对中位的原子链;它们的Fe（II）络合物在低温（-55 ℃）和25 ℃下可逆地氧化。C被不可逆地转换成μ-氧代二聚体。
Two strapped porphyrins, containing a chain of atoms linking 2 opposite meso-positions were synthesized; their Fe(II) complexes were oxygenated reversibly at low temperatures (-55 C) and at 25.degree. C were converted, irreversibly, into .mu.-oxo dimers.