Synthesis of silylboronic esters functionalized on silicon
Synthesis of silylboronic esters functionalized on silicon
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DOI：
10.1021/om0609867
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发表时间：
2007-02-26
期刊：
影响因子：
2.8
通讯作者：
Suginome, Michinori
中科院分区：
文献类型：
--
作者：
Ohmura, Toshimichi;Masuda, Kohei;Suginome, Michinori
New silylpinacolboranes bearing chloro, fluoro, alkoxy, and dialkylamino groups on silicon were synthesized in high yields via derivatization of [(diethylamino)diphenylsilyl]pinacolborane, which was prepared by reaction of [(diethylamino)diphenylsilyl]lithium with (isopropoxy)pinacolborane, and (chlorodimethylsilyl)pinacolborane, prepared by reaction of (dimethylphenylsilyl)pinacolborane with hydrogen chloride in the presence of a catalytic amount of aluminum chloride.
