Synthetic studies on borrelidin: enantioselective synthesis of the C1-C12 fragment.
Synthetic studies on borrelidin: enantioselective synthesis of the C1-C12 fragment.
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疏螺旋体素的合成研究：C1-C12 片段的对映选择性合成。
DOI：
10.1021/ol034243i
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发表时间：
2003
期刊：
影响因子：
--
通讯作者：
Theodorakis,EmmanuelA
中科院分区：
文献类型：
--
作者：
Vong,BinhG;Abraham,Sunny;Xiang,AlanX;Theodorakis,EmmanuelA
An efficient, enantioselective synthesis of the C1−C12 fragment2of borrelidin is presented. Construction of the “skipped” polymethylene chain of2was accomplished by iteration of Myers' alkylation, while formation of the C3 stereocenter was achieved by Roush's asymmetric allylboration methodology.
