MEASURE OF NONPLANARITY IN CONJUGATED ORGANIC-MOLECULES - WHICH STRUCTURALLY CHARACTERIZED MOLECULE DISPLAYS THE HIGHEST DEGREE OF PYRAMIDALIZATION
MEASURE OF NONPLANARITY IN CONJUGATED ORGANIC-MOLECULES - WHICH STRUCTURALLY CHARACTERIZED MOLECULE DISPLAYS THE HIGHEST DEGREE OF PYRAMIDALIZATION
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DOI：
10.1021/ja00165a020
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发表时间：
1990-04-25
影响因子：
15
通讯作者：
HADDON, RC
中科院分区：
文献类型：
--
作者：
HADDON, RC
结论取代基的性质对从醇到醇盐离子的C-0键长的变化影响很小。氢、甲基或氟的效果大致相同。通常对电荷的影响
Conclusions The change in C-0 bond length on going from an alcohol to its alkoxide ion is only to a small extent affected by the nature of the substituents. A hydrogen, methyl group, or fluorine is approximately equally effective. The usual effect on the charge