Photoionization and photofragmentation of singly charged positive and negative Sc3N@C80 endohedral fullerene ions

Photoionization and photofragmentation of singly charged positive and negative Sc3N@C80 endohedral fullerene ions
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单电荷正负 Sc3N@C80 内嵌富勒烯离子的光电离和光裂解

DOI:
10.1088/1742-6596/1412/20/202027
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发表时间:
2019
期刊:
Journal of Physics: Conference Series
影响因子:
--
通讯作者:
S. Schippers
S. Schippers
中科院分区:
--
文献类型:
--
作者:
A. Müller;Michael Martins;A. Kilcoyne;R. Phaneuf;J. Hellhund;Alexander Borovik;K. Holste;S. Bari;T. Buhr;S. Klumpp;A. Perry;S. Reinwardt;S. Ricz;K. Schubert;S. Schippers

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实验研究了气相中内嵌富勒烯离子Sc3N@C80+和Sc3N@C80-的光过程,重点是封装的三金属氮化物簇Sc 3 N对所观察到的反应产率的具体影响。在一个和两个电子去除通道中可见的主要贡献,获得了清晰的证据附近的Sc L边缘的光激发。实验是伴随着采用密度泛函理论(DFT)的模型计算。
Photoprocesses of the endohedral fullerene ions Sc3N@C80+ and Sc3N@C80− in the gas phase have been experimentally investigated with emphasis on the specific effects of the encapsulated trimetallic nitride cluster Sc3N on the observed reaction yields. Clear evidence of photoexcitation near the Sc L edge is obtained with the dominating contributions visible in the one- and two-electron-removal channels. The experiments are accompanied by model calculations employing density functional theory (DFT).
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影响因子: 2
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