Direct C-H Bond Arylation of (Hetero)arenes with Aryl and Heteroarylboronic Acids

Direct C-H Bond Arylation of (Hetero)arenes with Aryl and Heteroarylboronic Acids
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DOI:
10.1055/s-0029-1219234
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发表时间:
2010-04-01
影响因子:
2.6
通讯作者:
Saraf, Shuddham
Saraf, Shuddham
中科院分区:
化学4区
文献类型:
--
作者:
Guchhait, Sankar K.;Kashyap, Maneesh;Saraf, Shuddham

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A novel microwave-promoted protocol mediated by Mn(OAc)(3) was developed for the single-electron-transfer oxidative direct C-H bond arylation of (hetero)arenes with aryl and heteroarylboronic acids. Various electron-deactivated and electron-rich heteroarenes and benzene underwent successfully the direct arylation in this general process. The use of slight excess of heteroarene or benzene in this method was found to be sufficient.