Synthesis and spectral properties of iron(III) tetra-tert-butylphthalocyanine complexes
Synthesis and spectral properties of iron(III) tetra-tert-butylphthalocyanine complexes
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四叔丁基酞菁铁(III)配合物的合成及光谱性质
DOI：
10.1016/j.mencom.2017.09.012
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发表时间：
2017
影响因子：
1.9
通讯作者：
L. G. Tomilova
中科院分区：
文献类型：
--
作者：
I. D. Burtsev;T. Dubinina;Yana B. Platonova;A. Kosov;D. Pankratov;L. G. Tomilova
以酞菁配体和铁（III）盐为原料，高收率合成了两个四叔丁基酞菁铁（III）配合物；通过Mössbauer和EPR谱法证实了铁的氧化态。揭示了在分光光度滴定过程中存在酸碱平衡。t-Bu - PcFeCl配合物催化苯的氯化反应。
Two tetra-tert-butylphthalocyanine complexes of iron (III) were synthesized in high yields from the phthalocyanine ligand and iron (III) salts; the oxidation state of iron was confirmed by Mössbauer and EPR spectroscopy. The existence of an acid–base equilibrium during spectrophotometric titration was revealed. The t-Bu PcFeCl complex catalyzed chlorination of benzene.