AN UNUSUALLY STABLE THIONITRITE FROM N-ACETYL-D,L-PENICILLAMINE, X-RAY CRYSTAL AND MOLECULAR STRUCTURE OF 2-(ACETYLAMINO)-2-CARBOXY-1,1-DIMETHYLETHYL THIONITRITE
AN UNUSUALLY STABLE THIONITRITE FROM N-ACETYL-D,L-PENICILLAMINE, X-RAY CRYSTAL AND MOLECULAR STRUCTURE OF 2-(ACETYLAMINO)-2-CARBOXY-1,1-DIMETHYLETHYL THIONITRITE
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由 N-乙酰基-D,L-青霉胺、X 射线晶体和 2-(乙酰氨基)-2-羧基-1,1-二甲基亚硫酸盐的分子结构得出的异常稳定的亚硝酸盐
DOI：
10.1002/chin.197829195
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发表时间：
1978
期刊：
影响因子：
--
通讯作者：
G. Carnahan
中科院分区：
文献类型：
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作者：
L. Field;R. Dilts;R. Ravichandran;P. Lenhert;G. Carnahan
N-乙酰基-D，L-青霉胺（1）被HNO_2转化为亚硫硝酸盐（3），该亚硫硝酸盐作为固体是稳定的，在溶液中也是稳定的;给出了（3）的X-射线结构参数，并描述了均裂和异裂反应。
N-Acetyl-D,L-penicillamine (1) was converted by HNO2 into a thionitrite (3) which was stable as a solid and atypically so even in solution; X-ray structural parameters are given for (3), and both homolytic and heterolytic reactions are described.