Research on the preparation of ceramic tritium breeders in SICCAS

Research on the preparation of ceramic tritium breeders in SICCAS
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中科院陶瓷氚增殖体制备研究

DOI:
10.1016/j.fusengdes.2010.04.037
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发表时间:
2010-12
影响因子:
1.7
通讯作者:
Gu, Zhonghua
Gu, Zhonghua
中科院分区:
工程技术3区
文献类型:
--
作者:
Wen, Zhaoyin;Wu, Xiangwei;Xu, Xiaogang;Lin, Jiu;Gu, Zhonghua

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本文综述了制备不同形状的li2tio3和li4sio4鹅卵石、γ- lialo2陶瓷棒、γ- lialo2陶瓷环等陶瓷氚增殖剂的研究工作。采用新开发的水基溶胶-凝胶法制备了具有良好球形度的li2tio3和li4sio4陶瓷球,有望实现低成本、高效率的批量生产。通过在基体材料中引入适当的掺杂剂,li2tio3的离子电导率明显提高,这可能有助于氚的释放和库存性能。采用凝胶浇铸法和塑性成形法分别制备了γ- lialo2陶瓷棒和陶瓷环。研究发现,前驱体的流变学和化学流变学行为对制备过程有影响。
This paper summarized our research work on the preparation of ceramic tritium breeders with different shapes, such as Li2TiO3and Li4SiO4pebbles, γ-LiAlO2ceramic bars, γ-LiAlO2ceramic rings and so on. Li2TiO3and Li4SiO4ceramic spheres with favorable sphericity were obtained by a newly developed method, the water-based sol–gel process, which was expected to lead to a scale up to a low cost and efficient manufacturing process for mass production. The ionic conductivity of Li2TiO3was enhanced significantly by introducing appropriate dopants to the matrix materials, which was probably helpful to the release and inventory performance of the tritium. Gel-casting and plastic forming process were conducted to fabricate γ-LiAlO2ceramic bars and ceramic rings, respectively. It was found that the rheological and chemorheology behaviors of the precursors were influential to the fabrication process.
用于塑料成型的水性聚合物塑化 γ-LiAlO2 浆料的流变行为
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