CHEMISTRY OF HIGHER ORDER MIXED ORGANOCUPRATES. 2. REACTIONS OF EPOXIDES

CHEMISTRY OF HIGHER ORDER MIXED ORGANOCUPRATES. 2. REACTIONS OF EPOXIDES
复制标题

高阶混合有机铜酸盐的化学。

DOI：
10.1002/chin.198232115
复制
发表时间：
1982
期刊：
ChemInform
影响因子：
--
通讯作者：
R. Wilhelm
R. Wilhelm
中科院分区：
--
文献类型：
--
作者：
B. Lipshutz;J. Kozlowski;R. Wilhelm

文献摘要

被引文献

相似文献

通过取代反应形成碳-碳键是有机铜试剂在有机合成中继续发挥重要作用的特征模式之一。3据我们所知，我们最近描述了在第二个未激活的中心实施这一过程的第一个一般程序。这发生在没有来自还原和/或消除的明显竞争的情况下，通过通式R2Cu(CN)Li2，L 1作为环氧化物的更高阶混合有机铜酸盐的代理
The formation of carbon-carbon bonds via substitution reactions is one of the characteristic modes in which organocopper reagents continue to play an important role in organic synthesis. 3 We have recently described the first general procedure, to our knowledge, for effecting such a process at a secondary, unactivated center. This occurs without significant competition from reduction and/or elimination, through the agency of higher order mixedorganocuprates of the general formula R2Cu (CN) Li2, l. 1 As epoxide