Thermodynamics and Kinetics to Alloying Addition on In-Situ AlN/Mg Composites Synthesis via Displacement Reactions in Liquid Mg Melt

Thermodynamics and Kinetics to Alloying Addition on In-Situ AlN/Mg Composites Synthesis via Displacement Reactions in Liquid Mg Melt
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通过液态镁熔体中的置换反应合成原位 AlN/Mg 复合材料的合金化添加的热力学和动力学

DOI:
10.1007/s11661-009-9966-2
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发表时间:
2009-08
影响因子:
2.8
通讯作者:
Fan, Tongxiang
Fan, Tongxiang
中科院分区:
材料科学2区
文献类型:
--
作者:
Zhang, Di;Zhang, Congfa;Chen, Jianqi;Fan, Tongxiang

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基于威尔逊方程、扩展的米德马模型以及硬球理论,仅利用纯组分的相关量从理论上开发了新的模型,并将其应用于研究合金添加的热力学和动力学效应。
Based on the Wilson equation, extended Miedema model, and hard sphere theory, new models are developed theoretically only using the quantities of the pure component and are applied to investigate the thermodynamical and kinetic effect of alloying additions on in-situ AlN formation via displacement reaction in Mg-Al alloy melt. The results show that the alloying additions such as Si, Zn, and Cu can promote the formation of AlN in Mg-Al melt both in thermodynamics and kinetics. Meanwhile, other elements, including Mn, Nd, Ce, Ni, and La, must be matched properly in order to produce the desired reinforcement AlN in liquid Mg-Al melt.
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