Stereoselectivity in ring-closing olefin metathesis (RCM) of tethered dihexenoyl derivatives

Stereoselectivity in ring-closing olefin metathesis (RCM) of tethered dihexenoyl derivatives
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束缚二己烯酰基衍生物闭环烯烃复分解 (RCM) 的立体选择性

DOI：
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发表时间：
2002
期刊：
影响因子：
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通讯作者：
M. Nakagawa*
M. Nakagawa*
中科院分区：
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文献类型：
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作者：
M. Arisawa;H. Kaneko;A. Nishida;M. Nakagawa*

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考察了不同条件下不同二己烯酰基衍生物的闭环烯烃复分解反应。的E ∶ 确定了环状产物的所得双键的Z比。所得烯烃的立体化学在很大程度上受所用模板剂的影响。
Ring-closing olefin metatheses (RCM) of various tethered dihexenoyl derivatives were examined under various conditions. The E ∶ Z ratios of the resulting double bonds of the cyclic products were determined. The stereochemistry of the resulting olefins was influenced largely by the effects of the template used.