Synthesis and characterization of solid electrolyte structure material (LiAlO2) using different kinds of lithium and aluminum compounds for molten carbonate fuel cells

Synthesis and characterization of solid electrolyte structure material (LiAlO2) using different kinds of lithium and aluminum compounds for molten carbonate fuel cells
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用于熔融碳酸盐燃料电池的使用不同种类锂和铝化合物的固体电解质结构材料(LiAlO2)的合成和表征

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发表时间:
2016
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通讯作者:
Vecihe İnci̇rkuş
Vecihe İnci̇rkuş
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作者:
G. Özkan;G. Özkan;Vecihe İnci̇rkuş

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采用不同种类的锂铝化合物合成了熔融碳酸盐燃料电池固体电解质结构材料,并对其进行了表征。采用三种不同的锂化合物(LiOH·H2 O、LiNO 3和Li 2CO 3)和两种不同的铝化合物(Al 2 O3、Al(OH)3)进行合成操作。在合成过程中,所有反应在四种不同的pH水平(1.5、4、9.5和12)下进行,并在三种不同的温度下在露天条件下煅烧。通过热分析、结构分析和比表面积分析(TG-DTA、XRD和BET分析),认为Li 2CO 3和Al(OH)3合成LiAlO 2是一种方便的合成方法。
Synthesis and characterization of solid electrolyte structure material using different kinds of lithium and aluminum compounds for molten carbonate fuel cells have been carried out. Synthesis operations are performed using three different kinds of lithium compounds (LiOH.H 2 O, LiNO 3 and Li 2 CO 3 ) and two different kinds of aluminium compounds (Al 2 O 3 , Al(OH) 3 ). During the synthesis, all the reactions are conducted at four different p H levels (1.5, 4, 9.5 and 12) and are calcinated at three different temperatures in open air conditions. In the light of thermal, structural and surface area characterization (TG-DTA, XRD and BET analyses), it is concluded that LiAlO 2 which is produced with Li 2 CO 3 and Al(OH) 3, is found to be convenient.