Chemical oscillations and instabilities. Part 61. Temporary bistability and unusual oscillatory behavior in a closed Belousov-Zhabotinskii reaction system
Chemical oscillations and instabilities. Part 61. Temporary bistability and unusual oscillatory behavior in a closed Belousov-Zhabotinskii reaction system
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DOI：
10.1021/j100254a006
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发表时间：
1985-04
期刊：
影响因子：
--
通讯作者：
P. Ruoff;R. M. Noyes
中科院分区：
文献类型：
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作者：
P. Ruoff;R. M. Noyes
The Belousov2-Zhabotinsky3 reaction is probably the most investigated and best understood of all chemical oscillators. 4 Many of the previous studies have used the organic substrate malonic acid, CH2 (C02H) 2, which can undergo many complicated chemical processes. 5One of us6 has recently explored the cerium-catalyzed behavior with methylmaonicacid, CH3CH (C02H) 2. Only one hydrogen of this substrate is susceptible to bromination, and at least under some conditions7 89101112the stoichiometrically significant change in the overall system can evidently be described well to within about 3% by the unique
