Synthesis of the porphyrin-fused porphyrin, [2]porphyracene

Synthesis of the porphyrin-fused porphyrin, [2]porphyracene
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卟啉稠合卟啉的合成,[2]卟啉

DOI:
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发表时间:
2000
期刊:
影响因子:
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通讯作者:
Y. Sakata
Y. Sakata
中科院分区:
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文献类型:
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作者:
K. Sugiura;T. Matsumoto;Satoshi Ohkouchi;Y. Naitoh;T. Kawai;Y. Takai;Kantaro Ushiroda;Y. Sakata

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一种新的卟啉-稠合卟啉是由(卟啉)镍配合物与TeCl 4的低聚反应形成的;分离的化合物[2]卟啉通过光谱方法和使用扫描隧道显微镜的直接观察进行表征;激发能值为13460 cm-1(743 nm)是卟啉二聚体的最低值。
A novel porphyrin-fused porphyrin is formed by an oligomerization reaction of a (porphyrinato)nickel complex with TeCl4; the isolated compound, [2]porphyracene, was characterized by spectroscopic methods and direct observation using scanning tunnelling microscopy; the excitation energy value of 13460 cm–1 (743 nm) is the lowest value reported for porphyrin dimers.
DOI: 10.1126/science.8178169
发表时间: 1994-05-20
期刊: SCIENCE
影响因子: 56.9
作者:
LIN, VSY;DIMAGNO, SG;THERIEN, MJ
通讯作者: THERIEN, MJ