An Overview of Selective Oxidation of Alcohols: Catalysts, Oxidants and Reaction Mechanisms
An Overview of Selective Oxidation of Alcohols: Catalysts, Oxidants and Reaction Mechanisms
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DOI：
10.1007/s10563-015-9199-x
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发表时间：
2016-03
影响因子：
3
通讯作者：
Chen Xu;Chuanhui Zhang;Hong Li;Xueyuan Zhao;Liang Song;Xuebing Li
中科院分区：
文献类型：
--
作者：
Chen Xu;Chuanhui Zhang;Hong Li;Xueyuan Zhao;Liang Song;Xuebing Li
醇氧化成羰基化合物是有机合成中最基本的反应之一。为了实现高原子效率的脱氢反应，合适的催化剂和氧化剂被认为是获得最佳活性和醛/酮选择性的关键因素。本文对醇类脱氢反应的合理反应机理和催化体系进行了综述。
The oxidation of alcohols to carbonyl compounds is one of the most fundamental reactions in synthetic organic chemistry. In order to achieve the realization of dehydrogenation reactions with high atomic efficiency, suitable catalysts and oxidants are considered as the key factors to obtain the optimum activity and aldehydes/ketones selectivity. This review aims to make an overview on the reasonable reaction mechanism and promising catalytic system of alcohols dehydrogenation.