Energy and Volume Relations in the Solubilities of Some Ketones in Water.

Energy and Volume Relations in the Solubilities of Some Ketones in Water.
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DOI:
10.1021/j150389a002
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发表时间:
1939-02
期刊:
The Journal of Physical Chemistry
影响因子:
--
通讯作者:
P. Gross;J. Rintelen;J. H. Saylor
P. Gross;J. Rintelen;J. H. Saylor
中科院分区:
其他
文献类型:
--
作者:
P. Gross;J. Rintelen;J. H. Saylor

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RESULTSThe solubilities found for the ketones are given in table 1. These observed values were converted to vapor solubilities. The vapor solu-bility, C „, is defined as the concentration in the water which would be in equilibrium with thevapor of the substance under a standard pressure p, of 100 mm. at the temperaturein question. If C is the observed solu-bility and pL the vapor pressure of the liquid solute at the same temperature, then if Henry’s law holds