4 TRITERPENOID SAPONINS FROM DRIED ROOTS OF GYPSOPHILA SPECIES

4 TRITERPENOID SAPONINS FROM DRIED ROOTS OF GYPSOPHILA SPECIES
复制标题

DOI：
10.1016/0031-9422(91)85281-4
复制
发表时间：
1991-01-01
期刊：
PHYTOCHEMISTRY
影响因子：
3.8
通讯作者：
VUILHORGNE, M
VUILHORGNE, M
中科院分区：
生物学2区
文献类型：
--
作者：
FRECHET, D;CHRIST, B;VUILHORGNE, M

文献摘要

被引文献

相似文献

从满天星（Gypsophila paniculata）和满天星（G. arrostii。 它们的结构是使用同源和异源2D NMR技术的组合来阐明的，而无需求助于化学降解或修饰。 研究的皂苷是：3-O-β-D-吡喃半乳糖基-（1->2）-[β-D-吡喃木糖基-（1->3）]-β-D-吡喃葡萄糖醛酸基皂皮酸28-O-β-D-吡喃葡萄糖基-（1->3）-[β-D-吡喃木糖基-（1->4）]-α-L-吡喃鼠李糖基-（1->2）-β-D-吡喃岩藻糖苷; 3-O-β-D-吡喃半乳糖基-（1-->2）-[beta-D-吡喃木糖基-（1-->3）]-beta-D-吡喃葡萄糖醛酸基奎拉酸28-O-β-D-吡喃阿拉伯糖基-（1-->4）-beta-D-吡喃阿拉伯糖基-（1-->3）-beta-D-吡喃木糖基-（1--> 4）-α-L-吡喃鼠李糖基-（1-->2）-β-D-吡喃岩藻糖苷; 28-O-β-D-吡喃葡萄糖基-（1->3）-[β-D-吡喃木糖基-（1->4）]-α-L-吡喃鼠李糖基-（1->2）-β-D-吡喃岩藻糖苷; 3-O-β-D-吡喃木糖基-（1-->3）-[β-D-吡喃半乳糖基-（1-->2）]-β-D-吡喃葡萄糖醛酸基绞股蓝皂甙元28-O-β-D-吡喃葡萄糖基-（1-->3）-[β-D-吡喃木糖基-（1--> 3）]->4）]-α-L-吡喃鼠李糖基-（1->2）-β-D-吡喃岩藻糖苷。
Four new triterpenoid saponins were isolated from the roots of Gypsophila paniculata and G. arrostii. Their structures were elucidated using a combination of homo- and heteronuclear 2D NMR techniques, without having recourse to chemical degradation or modification. The saponins investigated are: 3-O-beta-D-galactopyranosyl-(1-->2)-[beta-D-xylopyranosyl-(-->3)]-beta-D-glucuronopyranosyl quillaic acid 28-O-beta-D-glucopyranosyl-(1-->3)-[beta-D-xylopyranosyl-(1-->4)]-alpha-L-rhamnopyranosyl-(1-->2)-beta-D-fucopyranoside; 3-O-beta-D-galactopyranosyl-(1-->2)-[beta-D-xylopyranosyl-(1-->3)]-beta-D-glucuronopyranosyl quillaic acid 28-O-beta-D-arabinopyranosyl-(1-->4)-beta-D-arabinopyranosyl-(1-->3)-beta-D-xylopyranosyl-(1-->4)-alpha-L-rhamnopyranosyl-(1-->2)-beta-D-fucopyranoside;?? 3-O-beta-D-glucopyranosyl-(1-->2)-beta-D-glucuronopyranosyl gypsogenin 28-O-beta-D-glucopyranosyl-(1-->3)-[beta-D-xylopyranosyl-(1-->4)]-alpha-L-rhamnopyranosyl-(1-->2)-beta-D-fucopyranoside; 3-O-beta-D-xylopyranosyl-(1-->3)-[beta-D-galactopyranosyl-(1-->2)]-beta-D-glucuronopyranosyl gypsogenin 28-O-beta-D-glucopyranosyl-(1-->3)-[beta-D-xylopyranosyl-(1-->4)]-alpha-L-rhamnopyranosyl-(1-->2)-beta-D-fucopyranoside.