Synthesis of hexadecacarbonylhexacobalt
Synthesis of hexadecacarbonylhexacobalt
复制标题
十六羰基六钴的合成
DOI：
10.1021/ic50075a046
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发表时间：
1969
影响因子：
4.6
通讯作者：
P. Chini
中科院分区：
文献类型：
--
作者：
P. Chini
关于钴亚基中的中性羰基存在相当大的混淆。已知钴产生CO2(CO)8和Co4(CO)I2，而Rh被认为产生Rh2(CO)8、Rh4(CO)i2和Rh6(CO)i6，而对于Ir，已经报道了IR2(CO)8和Ir4(CO)i2。1我们现在报道CoE-(CO)IE2的制备，它完成了一系列的钴化合物。稍后将给出一些关于IR6(CO)I6，3的分离的信息，并将引证一些证据来反对假设的存在
Considerable confusion has existed regarding the neutral carbonyls in the cobalt subgroup. Cobalt is known to give Co2 (CO) 8 and Co4 (CO) i2, and rhodium is stated to giveRh2 (CO) 8, Rh4 (CO) i2, and Rh6 (CO) i6, while for iridium both Ir2 (CO) 8 and Ir4 (CO) i2 have been reported. 1 We now report the preparation of Coe-(CO) ie2 which completes the series ofthe cobalt com-pounds. Later some information will be given about the isolation of Ir6 (CO) i6, 3 and some evidence will be adduced against the existence of thehypothetical