Copper-catalyzed Carboxylation of Aryl- and Alkenyltrialkoxysilanes
Copper-catalyzed Carboxylation of Aryl- and Alkenyltrialkoxysilanes
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DOI：
10.1002/ajoc.201700519
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发表时间：
2018
影响因子：
2.7
通讯作者：
T. V. Nguyen;Woo‐Jin Yoo;S. Kobayashi
中科院分区：
文献类型：
--
作者：
T. V. Nguyen;Woo‐Jin Yoo;S. Kobayashi
使用简单的铜盐作为催化剂，与CsF作为活化剂结合，使得宽范围的芳基-和烯基三烷氧基硅烷能够在CO2的大气压下进行羧化，以良好至高产率提供相应的羧酸。
The use of a simple copper salt as a catalyst, in conjugation with CsF as an activator, enabled a wide range of aryl- and alkenyltrialkoxysilanes to undergo carboxylation under atmospheric pressure of CO2 to afford the corresponding carboxylic acids in good to high yields.