Reactive Scattering as a Chemically Specific Analytical Probe of Liquid Surfaces.
Reactive Scattering as a Chemically Specific Analytical Probe of Liquid Surfaces.
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DOI：
10.1021/jz1013032
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发表时间：
2011-01
期刊：
影响因子：
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通讯作者：
C. Waring;P. Bagot;M. Costen;K. McKendrick
中科院分区：
文献类型：
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作者：
C. Waring;P. Bagot;M. Costen;K. McKendrick
在这一观点中，我们强调了“化学探针”物种（如原子或小自由基）从液体表面的反应散射的一些最新进展。我们特别强调这一领域从散射机制的纯动力学研究的演变。现在已经获得的机制理解已经足够成熟，可以将同样的方法用作有效的分析工具。使用这种方法来测量液体表面组成和结构是通过从一个常见的，咪唑基离子液体家族O（(3)P）原子的散射来说明的。
In this Perspective, we highlight some recent progress in the reactive scattering of "chemical probe" species such as atoms or small radicals from liquid surfaces. We emphasize in particular the evolution of this area from purely dynamical studies of the scattering mechanism. The mechanistic understanding that has now been gained is sufficiently mature to allow the same methods to be used as an effective analytical tool. The use of this approach to measure liquid-surface composition and structure is illustrated through the scattering of O((3)P) atoms from a common, imidazolium-based family of ionic liquids.