Ge(14)[Ge(SiMe(3))(3)](5)Li(3)(THF)(6): the largest metalloid cluster compound of germanium: on the way to fullerene-like compounds?
Ge(14)[Ge(SiMe(3))(3)](5)Li(3)(THF)(6): the largest metalloid cluster compound of germanium: on the way to fullerene-like compounds?
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Ge(14)[Ge(SiMe(3))(3)](5)Li(3)(THF)(6)：最大的锗类金属簇化合物：正在走向类富勒烯化合物？
DOI：
10.1039/b808279k
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发表时间：
2008
影响因子：
4.9
通讯作者：
A. Schnepf
中科院分区：
文献类型：
--
作者：
C. Schenk;A. Schnepf
GeBr与LiGe(Sime(3))(3)反应生成了最大的Ge(14)[Ge(Sime(3))(3)](5)Li(3)(THF)(6)的金属簇合物，其中14个Ge原子以空心球状排列在簇核中，表明在Ge的情况下，分子和固体的交界处也可能存在富勒烯类化合物。
The reaction of GeBr with LiGe(SiMe(3))(3) yields the largest metalloid cluster compound of germanium Ge(14)[Ge(SiMe(3))(3)](5)Li(3)(THF)(6), in which 14 germanium atoms are arranged as a hollow sphere in the cluster core, showing that in the case of germanium also fullerene-like compounds might be present in the borderland between the molecular and solid states.