A general synthesis of phosphaalkenes at zirconium with liberation of phosphaformamides.
A general synthesis of phosphaalkenes at zirconium with liberation of phosphaformamides.
复制标题
锆磷烯烃的一般合成并释放磷甲酰胺。
作者：
Andrew J. Roering;L. T. Elrod;Justin K. Pagano;Sarah L. Guillot;Stephanie M. Chan;J. Tanski;R. Waterman
报道了一种合成磷烯的原子经济的通用方法，该方法通过伯烷基或芳基膦与芳基或烷基异腈在锆上的净偶联。含磷配体可以通过与有机亲电试剂反应从锆中以磷酸甲酰胺的形式释放。
A general, atom-economical method for the synthesis of phosphaalkenes is reported via the net coupling of primary alkyl or aryl phosphines with aryl or alkyl isocyanides at zirconium. The phosphorus-containing ligand can be liberated as the phosphaformamide from zirconium by reaction with an organic electrophile.
DOI：
10.1002/asia.200700103
发表时间：
2007
期刊：
Chemistry, an Asian journal
影响因子：
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作者：
Song,Maoying;Donnadieu,Bruno;Soleilhavoup,Michele;Bertrand,Guy
通讯作者：
Bertrand,Guy