Aggregation of lithium and mixed thallium(I)–lithium amides through η3- and η6-π-arene interactions in the solid
Aggregation of lithium and mixed thallium(I)–lithium amides through η3- and η6-π-arene interactions in the solid
复制标题
锂和混合铊(I)-氨基锂通过固体中的 η3- 和 η6-π-芳烃相互作用聚集
DOI：
10.1039/a708139a
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发表时间：
1998
影响因子：
4.9
通讯作者：
D. Stalke
中科院分区：
文献类型：
--
作者：
K. Hellmann;C. Galka;L. Gade;T. Kottke;D. Stalke
合成了混合的锂-铊酰胺[C10 H6 {N[Li（thf）2] SiMe 3}{N（Tl）SiMe 3}]，并显示出在固体中通过η6-芳烃-铊配位聚集;对于部分溶剂化的均相锂酰胺[C10 H6 {N[Li（thf）] SiMe 3}{N（Li）SiMe 3}]，发现了相关的聚集模式，其显示出不寻常的η3-芳烃-锂相互作用。
The mixed Li–Tl amide [C10H6{N[Li(thf)2]SiMe3}{N(Tl)SiMe3}] has been synthesized and shown to aggregate via η6-arene–thallium coordination in the solid; a related pattern of aggregation is found for the partially solvated homometallic Li amide [C10H6{N[Li(thf)]SiMe3}{N(Li)SiMe3}] which displays an unusual η3-arene–lithium interaction.