Fine-tuning of the chromaticity of the emission color of organic-inorganic hybrids co-doped with EuIII, TbIII, and TmIII

Fine-tuning of the chromaticity of the emission color of organic-inorganic hybrids co-doped with EuIII, TbIII, and TmIII
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DOI:
10.1002/adfm.200290012
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发表时间:
2002-12-01
影响因子:
19
通讯作者:
Bermudez, VD
Bermudez, VD
中科院分区:
材料科学1区
文献类型:
--
作者:
Carlos, LD;Ferreira, RAS;Bermudez, VD

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报道了Eu3+, Tb3+和Tm3+共掺杂的有机-无机纳米结构杂化体的发射色度从红色到绿色的微调。将温度从200 K提高到300 K,颜色坐标从色度图的1黄绿色区域平滑地转向红色。这是讨论热激活的能量转移机制,从Tb3+的能量状态到杂化的发射水平。
A fine-tuning of the emission chromaticity from red to green is, reported for organic-inorganic nanostructured hybrids co-doped with Eu3+, Tb3+, and Tm3+. Raising the temperature from 200 to 300 K changes the color coordinates smoothly from the 1 yellowish-green region of the chromaticity diagram towards the red. This is discussed in terms of thermally activated energy-transfer mechanisms from Tb3+ energy states to the hybrid's emitting levels.