Synthesis and reactivity of 1-aryl-9H-thieno[3,4-b]chromon-9-ones

Synthesis and reactivity of 1-aryl-9H-thieno[3,4-b]chromon-9-ones
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1-芳基-9H-噻吩并[3,4-b]色酮-9-酮的合成和反应活性

DOI:
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发表时间:
2009
期刊:
影响因子:
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通讯作者:
K. Lyssenko
K. Lyssenko
中科院分区:
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文献类型:
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作者:
M. Krayushkin;K. S. Levchenko;V. Yarovenko;L. V. Christoforova;V. A. Barachevsky;Yury A. Puankov;T. Valova;O. Kobeleva;K. Lyssenko

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以2-甲基-4-色酮的溴代和二溴代衍生物为原料,在DMF中与硫代乙酰胺反应,合成了1-芳基-9-噻吩并[3,4-B]色酮。对噻吩并色酮类化合物进行了修饰,并对其荧光性质进行了研究。通过噻吩并色酮与酮醛反应合成了双噻吩并色酮。
Methods were developed for the synthesis of 1-aryl-9H-thieno[3,4-b]chromon-9-ones based on the reaction of bromo and dibromo derivatives of 2-methyl-4H-chromon-4-one with thioacetamide in DMF. The thienochromones were modified and their fluorescence properties were studied. Bis(thienochromones) were synthesized by the reaction of thienochromones with ketoaldehydes.