Polymerization of Phenylacetylene by Rhodium Complexes within a Discrete Space of apo-Ferritin
Polymerization of Phenylacetylene by Rhodium Complexes within a Discrete Space of apo-Ferritin
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DOI：
10.1021/ja901234j
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发表时间：
2009-05-27
影响因子：
15
通讯作者：
Watanabe, Yoshihito
中科院分区：
文献类型：
--
作者：
Abe, Satoshi;Hirata, Kunio;Watanabe, Yoshihito
在载铁蛋白的离散空间中，铑配合物促进了苯乙炔衍生物的聚合反应。催化反应提供了分子量有限和分子量分布窄的聚合物。这些结果表明，通过在蛋白质笼的内表面固定金属催化剂，蛋白质纳米笼具有作为各种反应空间的潜力。
Polymerization reactions of phenylacetylene derivatives are promoted by rhodium complexes within the discrete space of apo-ferritin in aqueous media. The catalytic reaction provides polymers with restricted molecular weight and a narrow molecular weight distribution. These results suggest that protein nanocages have potential for use as various reaction spaces through immobilization of metal catalysts on the interior surfaces of the protein cages.