Anomalous structural evolution in Cu50Zr50 glass-forming liquids

Anomalous structural evolution in Cu50Zr50 glass-forming liquids
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DOI:
10.1063/1.4813389
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发表时间:
2013-07
影响因子:
4
通讯作者:
N. Mauro;A. J. Vogt;Mark L. Johnson;J. Bendert;K. Kelton
N. Mauro;A. J. Vogt;Mark L. Johnson;J. Bendert;K. Kelton
中科院分区:
物理与天体物理2区
文献类型:
--
作者:
N. Mauro;A. J. Vogt;Mark L. Johnson;J. Bendert;K. Kelton

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The structural evolution of the Cu50Zr50 liquid and glass was determined from in situ high-energy X-ray diffraction measurements. The temperature dependence of the static X-ray structure factor for the glass was measured from room temperature to above the glass transition temperature. Data were obtained for equilibrium and supercooled liquids in a containerless environment using electrostatic levitation. The structure factors and the total pair correlation functions display an anomalous evolution, indicating a rapid acceleration of short-range atomic order in the liquid above, but near the glass transition temperature. This behavior contrasts sharply with that observed in high glass forming ability metallic liquids.