A new redox-active coordination polymer with cobalticinium dicarboxylate

A new redox-active coordination polymer with cobalticinium dicarboxylate
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DOI:
10.1021/ic049273b
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发表时间:
2004-09-20
影响因子:
4.6
通讯作者:
Uchida, F
Uchida, F
中科院分区:
化学2区
文献类型:
--
作者:
Kondo, M;Hayakawa, Y;Uchida, F

文献摘要

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制备了一种新型二维配位聚合物,其骨架中含有 1,1'-二羧酸钴 (ccdc),ccdc 作为独特的单阴离子二羧酸配体。该化合物显示出基于 ccdc 单元的高氧化还原活性。
A new two-dimensional coordination polymer with cobalticinium 1,1'-dicarboxylate (ccdc) incorporated in the framework has been prepared, the ccdc functioning as unique monoanionic dicarboxylate ligands. The compound shows a high redox activity based on the ccdc units.