Naphthyl-substituted Pentamethylcyclopentadienyl Ligand and its Sm(II) Bent-metallocene Complexes with Solventinduced Structure Change
Naphthyl-substituted Pentamethylcyclopentadienyl Ligand and its Sm(II) Bent-metallocene Complexes with Solventinduced Structure Change
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萘基取代的五甲基环戊二烯基配体及其溶剂诱导结构变化的 Sm(II) 弯曲茂金属配合物
DOI：
10.1039/c1dt11844g
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发表时间：
2012
期刊：
影响因子：
--
通讯作者：
Hidetaka Nakai
中科院分区：
文献类型：
--
作者：
Takeshi Yatabe;Masaki Karasawa;Kiyoshi Isobe;Seiji Ogo;Hidetaka Nakai
合成并表征了一个萘基取代的五甲基吡啶配体（CpNaph = η5-C5 Me 4CH 2C 10 H7）及其Sm（II）配合物[Sm（CpNaph）2（THF）x]（1：x = 2，2：x = 0）。在溶剂诱导下，二THF溶剂化的紫色配合物1和非溶剂化的深绿色配合物2之间发生可逆转化。
A naphthyl-substituted pentamethylcyclopentadienyl ligand (CpNaph = η5-C5Me4CH2C10H7) and its Sm(II) complexes [Sm(CpNaph)2(THF)x] (1: x = 2, 2: x = 0) have been prepared and characterised. The solvent-induced reversible conversion between the di-THF solvated purple complex 1 and the un-solvated dark green complex 2 is presented.